Vanadium Oxide Nanorods: Synthesis, Morphology, and Luminescence Characteristics

Authors

  • Kajal Thagela Centre for Nanoscience and Nanotechnology, Jamia Millia Islamia, New Delhi, India.
  • Hafiz A. K. Centre for Nanoscience and Nanotechnology, Jamia Millia Islamia, New Delhi, India.

DOI:

https://doi.org/10.61343/jcm.v3i02.68

Keywords:

V2O5, Hydrothermal, Nanorods (NRs), Photodetector

Abstract

A highly cost-effective synthesis approach has been adopted to prepare stable V2O5 nanorods for energy storage device applications. The as synthesized nanorods are thoroughly characterized using advanced techniques, including scanning electron microscopy (SEM), X- ray diffraction (XRD), UV visible and photoluminescence (PL). The mentioned techniques were performed to provide the valuable insight into the morphological, structural, optical and photoluminescence properties of as-synthesized V2O5 nanorods. X-ray diffraction exhibits the structural properties with the highest Bragg’s angle observed at 8.66 degree. Surface morphology of the as prepared and calcinated nanorod’s samples was studied by using the scanning electron microscope (SEM). The observed bandgap of NRs was calculated using tauc- plot and achieved at 2.61 eV. The photoluminescence spectroscopy demonstrates the luminescence behaviour of as synthesized nanorods. Aforementioned synthesis and results achieved through characterizations exhibits its potential suitability for photodetector applications.

References

Mounasamy, V., Srividhya, G., & Ponpandian, N. (2023), "Well-defined 2D Transition Vanadium Pentoxide (V₂O₅) Flat Nanorods with Large-Scale Synthesis Feasibility as an Electrocatalyst for the Oxygen Evolution Reaction (OER)", Energy Advances, 2(6), 1234-1245. doi:10.1039/d3ya00100h.

Zhang, S., Li, Y., & Wang, J. (2018), "V₂O₅-Based Nanomaterials: Synthesis and Their Applications", RSC Advances, 8(15), 7890-7910. doi:10.1039/c7ra12523b.

Chen, L., Liu, X., & Zhang, H. (2019), "Synthesis of Vanadium Oxide Nanorods Coated with Carbon: Characterization and Electrochemical Properties", Journal of Solid State Electrochemistry, 23(9), 2455-2463. doi:10.1007/s11581-019-03203-1.

S. S. Karade, S. Lalwani, J.-H. Eum, and H. Kim, “Coin cell fabricated symmetric supercapacitor device of two-steps synthesized V2O5 Nanorods”, J. Electroanal. Chem., vol. 864, p. 114080, May 2020, doi: 10.1016/j.jelechem.2020.114080.

J. Pan et al., “Microwave-assisted hydrothermal synthesis of V2O5 nanorods assemblies with an improved Li-ion batteries performance”, Mater. Res. Bull., vol. 74, pp. 90–95, Feb. 2016, doi: 10.1016/j.materresbull.2015.10.020.

W. M. Zhang, X. L. Wu, J. S. Hu, Y. G. Guo, and L. J. Wan, “α-Fe2O3 nanotubes in gas sensor and lithium-ion batteries applications”, Adv Mater, vol. 17, pp. 582–586, 2005.

“Vanadium based materials as electrode materials for high performance supercapacitors - ScienceDirect.” Accessed: Dec. 14, 2024. [Online]. Available: https://www.sciencedirect.com/science/article/abs/pii/S0378775316310382

I. Pradeep, E. Ranjith Kumar, N. Suriyanarayanan, Ch. Srinivas, and M. V. K. Mehar, “Effects of doping concentration on structural, morphological, optical and electrical properties of tungsten doped V2O5 nanorods”, Ceram. Int., vol. 44, no. 6, pp. 7098–7109, Apr. 2018, doi: 10.1016/j.ceramint.2018.01.149.

M. S. Raman, N. S. kumar, J. Chandrasekaran, R. Priya, P. Baraneedharan, and M. Chavali, “Thermal annealing effects on structural, optical and electrical properties of V2O5 nanorods for photodiode application”, Optik, vol. 157, pp. 410–420, Mar. 2018, doi: 10.1016/j.ijleo.2017.11.030.

T. Zahra et al., “Fabrication of V2O5@g-C3N4 nanocomposite by hydrothermal route for use as an improved electrochemical property in supercapacitor applications”, J. Energy Storage, vol. 87, p. 111470, May 2024, doi: 10.1016/j.est.2024.111470.

M. R. Charlotte and L. R. Viannie, “Tailoring vanadium pentoxide nanoparticles for humidity sensing: impact of microwave annealing”, J. Mater. Sci., vol. 59, no. 48, pp. 22034–22052, Dec. 2024, doi: 10.1007/s10853-024-10485-y.

“Facile Fabrication of Composite Vanadium Oxide Thin Films with Enhanced Thermochromic Properties | ACS Applied Materials & Interfaces”, Accessed: Dec. 14, 2024. [Online]. Available: https://pubs.acs.org/doi/abs/10.1021/acsami.9b11376

M. Kaseem, A. R. Safira, M. Aadil, T. T. Thanaa, and A. Fattah-alhosseini, “Developing an efficient anticorrosive system through advanced modification of plasma-electrolyzed MgO with CeNiLDH complexed with V₂O₅ nanoparticles and (2E)-But-2-enedioic acid”, J. Magnes. Alloys, vol. 12, no. 10, pp. 4205–4218, Oct. 2024, doi: 10.1016/j.jma.2024.10.015.

B. Singh et al., “Anomalous lattice behavior of vanadium pentaoxide (V2O5): X-ray diffraction, inelastic neutron scattering and ab initio lattice dynamics”, Phys. Chem. Chem. Phys., vol. 19, no. 27, pp. 17967–17984, Jul. 2017, doi: 10.1039/C7CP01904A.

D. Mc Nulty, “Synthesis, structure and electrochemical performance of V₂O₅ nanostructures as cathode materials for advanced lithium-ion batteries”, thesis, University of Limerick, 2014. doi: 10.34961/researchrepository-ul.23654103.v1.

A. S. Rao, B. S. Sannakashappanavar, A. Jayarama, and R. Pinto, “Study of rectifying properties and true Ohmic contact on Sn doped V2O5 thin films deposited by spray pyrolysis method”, Results Chem., vol. 7, p. 101533, Jan. 2024, doi: 10.1016/j.rechem.2024.101533.

“Optoelectronic and Electrochemical Properties of Vanadium Pentoxide Nanowires Synthesized by Vapor-Solid Process”, Accessed: Dec. 14, 2024. [Online]. Available: https://www.mdpi.com/2079-4991/6/8/140

J. Yao, Y. Li, R. C. Massé, E. Uchaker, and G. Cao, “Revitalized interest in vanadium pentoxide as cathode material for lithium-ion batteries and beyond”, Energy Storage Mater., vol. 11, pp. 205–259, Mar. 2018, doi: 10.1016/j.ensm.2017.10.014.

D. Jha, B. Somapur, A. Paul, C. Kavitha, and N. Kambhala, “Enhanced super capacitance performance of V₂O₅·nH₂O/g-C₃N₄ nanocomposites: Synthesis, characterizations, and electrochemical properties”, Mater. Chem. Phys., vol. 332, p. 130244, Feb. 2025, doi: 10.1016/j.matchemphys.2024.130244.

S. Ruzgar, “The effect of strontium doping on optoelectrical properties of V2O5/p-Si photodiode,” Opt. Mater., vol. 157, p. 116087, Nov. 2024, doi: 10.1016/j.optmat.2024.116087.

Downloads

Published

2025-05-04

How to Cite

1.
Thagela K, Hafiz A. K. Vanadium Oxide Nanorods: Synthesis, Morphology, and Luminescence Characteristics. J. Cond. Matt. [Internet]. 2025 May 4 [cited 2025 May 10];3(02):95-9. Available from: https://jcm.thecmrs.in/index.php/j/article/view/68

Issue

Section

Research Article

Categories