Chemical and Green Synthesis of CuO Nanoparticles using Carica papaya leaf Extract: Structural and Optical properties
DOI:
https://doi.org/10.61343/jcm.v2i02.62Keywords:
Copper oxide, Carica papaya leaf extract, Chemical and green synthesis, Optical propertiesAbstract
This article describes the synthesis of CuO nanoparticles through a two different synthesis routes, namely a chemical co-precipitation and green synthesis route using Carica papaya leaf extract and their optical properties. The samples were investigated for their structural and optical properties through X-ray diffraction, scanning electron microscopy, Fourier transfer infrared, UV absorption, photoluminescence and time resolved spectroscopy. The XRD spectra of both samples demonstrate the CuO crystallizes in a monoclinic phase with particle sizes ranging from 20-25 nm. SEM pictures of samples showed the highly agglomerated and spherical particles are formed. The peaks in FTIR spectra are located between 600-1000 cm-1, confirming the formation of CuO phase. The observed shift in UV absorption edge and PL peak of both samples is the result of size quantization and various surface defects. The carrier life time study of both samples revealed the recombination rate of exciton depend on particle size and surface defects. The results of this study indicates CuO is an alternative material for solar cell and optoelectronic devices.
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