Peroxide-Cured Silicone Rubber Composites: Structural, Morphological, and X-ray Detector Performance Analysis
DOI:
https://doi.org/10.61343/jcm.v3i02.140Keywords:
polymer composite, SEM, EDAX, peroxide curingAbstract
In this study, a soft and flexible polymer composite of silicone rubber was synthesized by incorporating varying concentrations of a peroxide curing agent using the solution casting method, a cost-effective method at room temperature. The synthesized composites were characterized through Energy Dispersive X-ray Analysis (EDAX) and Scanning Electron Microscopy (SEM) to determine elemental composition and surface morphology. SEM micrographs revealed a smooth surface with uniformly distributed crystallites, forming a matrix-like arrangement. Additionally, X-ray switching response measurements were recorded at different voltages to evaluate the detector performance of the composite material. It was observed that detector is showing the photo-response but the difference in photocurrent and dark current needs to be enhanced by adding conducting fillers in the matrix of silicone rubber. The results suggest that peroxide concentration significantly influences the structural, morphological, and detector response properties of the silicone rubber composite, offering valuable insights into optimizing curing conditions for enhanced material performance and detector efficiency.
References
S. Diao, F. Dong, J. Meng, P. Ma, Y. Zhao, and S. Feng, “Preparation and properties of heat-curable silicone rubber through chloropropyl/amine crosslinking reactions”, Materials Chemistry and Physics, vol. 153, pp. 161–167, Mar. 2015, doi: 10.1016/j.matchemphys.2014.12.048.
M. Azevedo, A.-M. Monks, R. C. Kerschbaumer, S. Schlögl, and C. Holzer, “Peroxide-Based Crosslinking of Solid Silicone Rubber, Part I: Insights into the Influence of Dicumylperoxide Concentration on the Curing Kinetics and Thermodynamics Determined by a Rheological Approach”, Polymers, vol. 14, no. 20, p. 4404, Oct. 2022, doi: 10.3390/polym14204404.
“The Polymeric Organosiloxanes”, in Chemistry and Technology of Silicones, Elsevier, 1968, pp. 246–331. doi: 10.1016/B978-0-12-520750-8.50029-4.
E. Yilgör and I. Yilgör, “Silicone containing copolymers: Synthesis, properties and applications”, Progress in Polymer Science, vol. 39, no. 6, pp. 1165–1195, Jun. 2014, doi: 10.1016/j.progpolymsci.2013.11.003.
R. Chaudhari, S. Kumar Sharma, C. Ravi Kant, and A. Garg, “Investigations on low energy X-ray induced strong radiation-matter interaction phenomena in polymer-BiI3 hybrid materials for room temperature radiation detectors”, Materials Today: Proceedings, vol. 67, pp. 478–482, 2022, doi: 10.1016/j.matpr.2022.06.584.
R. Chaudhari, A. Garg, K. Singh, M. Tomar, V. Gupta, and C. RaviKant, “Bismuth tri-iodide-polystyrene composite for X-rays switching applications at room temperature”, Radiation Physics and Chemistry, vol. 186, p. 109538, Sep. 2021, doi: 10.1016/j.radphyschem.2021.109538.
H. M. Thirimanne et al., “High sensitivity organic inorganic hybrid X-ray detectors with direct transduction and broadband response”, Nat Commun, vol. 9, no. 1, p. 2926, Jul. 2018, doi: 10.1038/s41467-018-05301-6.
I. K. Hong and S. Lee, “Cure kinetics and modeling the reaction of silicone rubber”, Journal of Industrial and Engineering Chemistry, vol. 19, no. 1, pp. 42–47, Jan. 2013, doi: 10.1016/j.jiec.2012.05.006.

Downloads
Published
How to Cite
Issue
Section
Categories
License
Copyright (c) 2025 Bhawna, Kusum, Kulvinder Singh, Alka Garg

This work is licensed under a Creative Commons Attribution 4.0 International License.
Copyright© by the author(s). Published by journal of Condensed Matter. This is an open access article distributed under the terms of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original author(s) and source are credited.